Geochemical variations of anatectic melts in response to changes of P-T-H2O conditions: Implication for the relationship between dehydration and hydration melting in the Himalayan orogen

CHEMICAL GEOLOGY(2024)

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摘要
The anatectic mechanism is the most fundamental criterion in determining the petrogenetic relationship between migmatite, granulite and granite at convergent plate margins. Although two main anatectic mechanisms, namely water-absent (dehydration) and water-fluxed (hydration) melting, have been identified in many collisional orogens, their spatiotemporal relationship and genetic connection remain obscure. To address this issue, we conduct an integrated study of forward phase equilibrium and trace element modelling for partial melting of metapelite in the Himalayan orogen. The results are used to decipher changes of phase relation and melt composition in response to changes of temperature, pressure and water content. Pressure and water content mainly affect the solidus and evolving residual mineral assemblages, whereas temperature controls the anatectic reaction. Hydration melting at lower pressure and temperature would produce anatectic melts with relatively high SiO2, FeOT + MgO, CaO, K2O, and Ba contents and SiO2/Al2O3 ratios, but low Al2O3 and Na2O contents and Na2O/K2O and Rb/Sr ratios. In contrast, dehydration melting at higher pressure and temperature would generate anatectic melts with relatively high Al2O3 and Na2O contents and Na2O/K2O and Rb/Sr ratios, but low SiO2, FeOT + MgO, CaO, K2O, and Ba contents and SiO2/Al2O3 ratios. A comparison of geochemical compositions between the modelled melts and the two groups of well-characterized leucogranites in the Himalayan orogen indicates that the coeval dehydration and hydration melting would likely occur at the deeper and shallower crustal levels, respectively. In combination with the secular evolution of metamorphic facies series in the Himalayan orogen, we propose a spatiotemporally coupled dehydration-hydration melting mechanism. The early metamorphism at lower geothermal gradients would result in metamorphic dehydration in the lower crust and hydration in the upper crust during the syn-collisional period in the Early Cenozoic. As a result, the later metamorphism at higher geothermal gradients would lead to dehydration melting in the lower crust and hydration melting in the upper crust during the post-collisional period in the Late Cenozoic. This study highlights the applicability of phase equilibrium and trace element modelling to reveal the geochemical variations of anatectic melts in response to changes of P-T-H2O conditions. This provides new insights into the relationship between dehydration and hydration melting in collisional orogens.
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关键词
Himalayan orogen,Metapelite,Leucogranite,Anatectic mechanism,Dehydration melting,Hydration melting
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