Selective occupancy of Fe substitution enhance the room-temperature ferromagnetism of (FexNi1-x)2P nanocrystals: Experimental and theoretical studies
PHYSICA B-CONDENSED MATTER(2024)
摘要
Understanding the heteroatoms occupancy in metal phosphides is significant to regulate their properties. (FexNi1-x)(2)P (0 <= x <= 0.5) nanocrystals were prepared by thermal decomposition. Effects of Fe substitution on structure, morphology and magnetic properties were studied. As the Fe content increases, (FexNi1-x)(2)P maintain hexagonal structure with morphologies changing from sphere to irregular sheet. Atomic HAADF-STEM image reveals that the atom configuration matches well with [001] crystallographic orientation. (FexNi1-x)(2)P nanocrystals show room-temperature ferromagnetism. The Ms values and magnetocrystalline anisotropy are enhanced by increasing Fe substitution. The Ms value of (Fe05Ni0.5)(2)P reaches 2.092 emu/g, 19.5 times larger than Ni2P. XPS and M & ouml;ssbauer spectra show that Fe2+/Fe3+ selectively occupy tetrahedral and pyramidal positions due to the difference of ionic radius, resulting in enhanced room-temperature ferromagnetism. First-principles calculations show that Fe substitution can induce ferromagnetic ordering in Ni2P, and Fe substitution in pyramidal positions induces larger magnetic moment, further confirming the experimental results.
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关键词
FexNi1-x)2P,Ferromagnetism,Mo center dot ssbauer spectroscopy,First-principles calculations
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