Anti-Entropy Aggregation of Minority Groups in Polymers: Design and Applications.

Minority groups are non-repeating units with very low content that inevitably exist in polymers. Typically, these minority groups are easily surrounded by the majority of repeating units and randomly dispersed, maximizing the entropy of minority groups. In the concept, anti-entropy aggregation (AEA) of minority groups is described, and different pathways are outlined. They are polymer crystallization-driven AEA, supramolecular interaction-induced AEA, phase separation-confined AEA, and hierarchical interactions-driven AEA. Typical applications of AEA materials are also presented, including fluorescence probes, self-healing materials, ion transporting regulation, and osmotic energy conversion. The concept of AEA is expected to inspire the fabrication of novel functional systems.