Green synthesis of bio-based flame retardant/natural rubber inorganic-organic hybrid and its flame retarding and toughening effect for polylactic acid.

Polylactic acid (PLA) has garnered significant interest as a bio-based polymer due to its favorable thermal and processing characteristics, as well as its notable economic and environmental benefits. However, the drawbacks such as flammability and poor toughness of PLA severely constrained its applications in more fields. Here, based on the outstanding flame-retardant properties of core-shell flame retardant (CSFR) and the toughening potential of natural rubber (NR), we synthesized inorganic-organic hybrid of CSFR-NR using an aqueous synthesis to synchronous optimization of the comprehensive performance of PLA. The as-prepared CSFR-NR with "hard core and soft shell" possess the ability to promote char formation and facilitate uniform dispersion in the PLA matrix. Consequently, the PLA/CSFR-NR showed an excellent flame retardancy with the limiting oxygen index (LOI) value of 31.5 % and UL-94 V-0 rating and synergistic toughening effect with absolutely improvement in elongation at break and notched izod impact strength, achieving a balance between the fire safety and mechanical performance. Moreover, the degradation rate of PLA has also been substantially promoted by CSFR-NR in simulated seawater. Hence, this study offers a straightforward, efficient, and environmentally friendly strategy for creating high-performance flame retardant and toughened bioplastics.