Diurnal variation characteristics and meteorological causes of autumn ozone in the Pearl River Delta, China

This study investigates the diurnal variation of ozone (O3) in the Pearl River Delta (PRD) during autumn from 2016 to 2021, focusing on the main O3 modes and their relationship with meteorological conditions. Utilizing Kmeans clustering, four patterns of O3 variation were identified: Cluster 1 (extremely low O3), Cluster 2 (close to autumn average), Cluster 3 (abnormally high O3 at night), and Cluster 4 (extremely high O3). In Cluster 1, the PRD was situated on the northwest side of the western Pacific subtropical high (WPSH), resulting in increased cloud cover, weakened radiation, and the lowest O3 growth rate during the day, with weak nighttime changes. Cluster 2 presents O3 changes under normal autumn conditions, closely resembling the autumn average. In Cluster 3, the PRD was located between continental high pressure and the low-pressure system over the South China Sea. The enhanced horizontal pressure gradient led to an increase in the horizontal wind speed, promoting the formation of a low-level jet (LLJ). The LLJ caused decoupling between the residual layer and stable boundary layer at night, leading to increased surface O3 concentration and a higher background O3 concentration before sunrise the next day. In Cluster 4, favorable meteorological conditions for O3 generation and accumulation were created by the influence of the WPSH and peripheral tropical cyclones. O3 rapidly increased during the day, reaching extremely high values in the afternoon, with an exceedance rate of 80 %. Comparing the four diurnal patterns and their meteorological conditions highlights the significance of meteorological processes in O3 variations.