Ba6RE2Ti4O17 (RE= Nd, Sm,Gd, Dy-Yb): A family of Rare-earth based layered triangular lattice magnets

Rare-earth-based triangular-lattice magnets provide the fertile ground to explore the exotic quantum magnetic state. Herein, we report a new family of RE-based triangular-lattice magnets Ba6RE2Ti4O17(RE= rare earth ions) crystallized into the hexagonal structure with space group of P63 mmc, where magnetic rare earth ions form an ideal triangular lattice within the ab-plane and stack in an AA -type fashion along the c-axis. The low-temperature magnetic susceptibility results reveal all the serial compounds have the dominant antiferromagnetic interactions and an absence of magnetic ordering down to 1.8 K. The magnetization and electron spin resonance results indicate distinct magnetic anisotropy for the compounds with different RE ions. Moreover, Ba6Nd2Ti4O17 single crystal is successfully grown and it exhibits strong Ising like anisotropy with magnetic easy-axis perpendicular to the triangle-lattice plane, being a candidate to explore quantum spin liquid state with dominant Ising-type interaction.