Environmental analysis of nylon 6,6 production from gamma-valerolactone derived from kenaf
INDUSTRIAL CROPS AND PRODUCTS(2023)
摘要
Nylon, known for its outstanding physical properties, durability, and affordability, is in high demand across various industries. The majority of nylon is currently produced using petroleum-based raw materials, which causes negative environmental impacts such as greenhouse gas emission and fossil resource depletion. This has motivated research and development of eco-friendly production methods using biomass, we propose the environmental feasibility of kenaf-based nylon production strategy in the Republic of Korea. This study carries out a life cycle assessment (LCA) for analyzing the global warming potential (GWP) and fossil resource scarcity (FRS) of nylon 6,6 production from gamma-valerolactone (GVL) derived from kenaf. The life cycle inventory is analyzed based on the simulation data of the GVL-to-nylon 6,6 process and the two major environmental impacts are quantified when the biorefinery is operated at the Saemangeum agro-bio industrial cluster in Jeollabuk-do in Republic of Korea. The nylon 6,6 production in the Saemangeum can effectively reduce the GWP (61%) and FRS (67%) compared to the conventional nylon 6,6 production. Furthermore, if the GWP of the two materials used in the production of nylon 6,6 (HMDA, NaOH) can be reduced by 50%, the GWP per kilogram of nylon 6,6 produced will be reduced by 43% (1.91 kg CO2 eq.).
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关键词
Nylon 6, 6,Gamma-valerolactone,Kenaf,Biorefinery,Process synthesis,Life cycle assessment
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