The response of organic carbon fractions in sediment to rainfall characteristics and slope lengths: Based on four-years on-site monitoring data

The effect of soil erosion processes on the properties of sediment and organic carbon fractions is not well understood under complex erosion environments, such as various rainfall characteristics and transport distances, which leads to a gap in knowledge regarding the role of soil erosion in the global carbon cycle. This study investigated the impact of different rainfall characteristics (patterns and parameters) and slope lengths (5 m similar to 20 m) on the sediment yield, particle size distribution (PSD) and properties of organic carbon fractions on China's Loess Plateau. The results show that runoff was highest under rainfall pattern A (extreme rainfall), while the sediment concentration peaked under rainfall pattern B (heavy rainfall), with significant correlation with slope length, rainfall intensity, kinetic energy, rainfall erosivity and precipitation (p less than 0.05). Silt-and clay-sized fractions were transported as primary particles and enriched under rainfall patterns B and C with no differences between slope lengths. The enrichment ratio (ER) of sediment, effective and ultimate particles were primarily influenced by rainfall intensity-related parameters. In contrast, the aggregation ratio (AR) tended to be influenced by rainfall kinetic energy. The content and loss of organic carbon fractions correlated to rainfall parameters and slope length, although no significant difference was observed between different rainfall patterns and slope lengths. Lost organic carbon fractions were predominantly Mineral-associated organic carbon (MOC), with great enrichment under rainfall pattern C and rapid depletion as the slope length increased. Structural equation models (SEM) indicated the effect of rainfall characteristics and slope length on organic carbon loss was mainly due to the regulation of soil loss and particle size distribution of sediment in selective transport erosion processes. We highlighted the need to consider the effect of soil erosion and particle size distribution comprehensively on the carbon cycle from the perspective of organic carbon fractions to describe the potential effects of soil erosion on the carbon budget quantitatively, especially in complex environmental conditions with consideration of scale effect.