An experimental assessment of seawater alternating near-miscible CO2 for EOR in pre-salt carbonate reservoirs

Enhanced oil recovery (EOR) methods considering the injection of seawater and CO2 have been widely investigated and applied in the Brazilian pre-salt fields. The high availability of these fluids in offshore facilities makes seawater alternating CO2 (CO2WAG) a viable and environmentally friendly EOR method. It combines the advantages of seawater injection and CO2 injection to improve fluid mobility control and viscous fingering attenuation. In this study, in addition to the core flooding test of secondary seawater flooding and the tertiary CO2WAG, different experimental determinations provided a better understanding of the mechanisms related to the EOR methods applied to a carbonate core composed mainly of dolomite, and their interactions with pre-salt oil, brines and CO2. A 13.30% incremental oil recovery was achieved by alternating seawater with CO2. Considering formation brine, non-carbonated seawater, or seawater saturated with CO2, contact angle measurements revealed that the wettability alteration is not significant when dolomite is slightly water-wet, even in the presence of CO2. On the other hand, measures of brine/oil, brine/CO2/oil and CO2/oil interfacial tension emphasize the beneficial effects of this gas for EOR, in near-miscible conditions. This is achieved by the reduction of capillary and interfacial forces that act by trapping the oil in the pores of the medium. The brine salinity, the presence of magnesium in dolomite and the oil's low TAN/TBN ratio proved to be essential factors in determining the slightly water-wet wettability of the dolomitic rock and the interfacial tension between the phases. Furthermore, for the experiments carried out in the presence of brine with solubilized CO2, a considerable variation in the oil drop volume was observed due to the mass transfer of CO2 between the phases. Finally, experimental results showed that the additional oil recovery was mainly associated with oil swelling, viscosity reduction, and mobility increase, which occur even in near-miscible conditions during CO2WAG.