Electrochemical Storage of Ammonium Versus Metal Ions in Bimetallic Hydroxide for Sustainable Aqueous Batteries
ADVANCED FUNCTIONAL MATERIALS(2024)
摘要
Aqueous batteries with high safety and cost efficiency usually employ metallic cations as charge carriers. Recently, ammonium (NH4+) ion batteries using the nonmetal NH4+ as a charge carrier exhibit distinct electrochemical features from conventional aqueous batteries. Herein, the electrochemical performances of a bimetallic hydroxide material are systematically studied with different charge carriers in the electrolytes, including NH4+, as well as the conventional monovalent metallic cations K+ and Na+, respectively. Electrochemical results indicate that the charge storage process using NH4+ as the working ions exhibits a higher discharge plateau, smaller electrochemical polarization, and larger discharge capacity than that using conventional metallic charge carriers. Experimental characterizations and theoretical calculations suggest that the strong interaction between NH4+ and the electrode material, as well as the low NH4+-ion diffusion barrier lead to these superior electrochemical features. The assembled NH4+-ion battery exhibits a good energy density of 123 Wh kg(cathode+anode)-1 at the power density of 480 W kg(cathode+anode)-1. These fundamental findings are important for developing good safety, low-cost, and high-energy aqueous batteries with sustainable NH4+ charge carriers. Electrochemical performances of a bimetallic hydroxide are systematically studied with different charge carriers in aqueous electrolytes, including nonmetal NH4+, and conventional K+ and Na+ ions. NH4+ exhibits stronger adsorption on the electrode surface and a lower solid-state diffusion barrier in the electrode, leading to a higher discharge plateau and faster electrode reaction kinetics.image
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关键词
ammonium ion batteries,bimetallic hydroxides,charge carrier,high performance,mechanism studies
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