Synthesis of bioethanol from mixed vegetable wastes: Experimental methodology and characterization

Bioethanol has been identified as a renewable product with high potential for application as biofuel. On the other hand, high volumes of agri-food residues are generated daily. Such residues have potential as raw materials for industrial bioethanol production. There is a significant advance in the synthesis of biofuels from fruit and vegetable residues; however, most of the studies are focused on the conversion of a single type of raw material, limiting the application of the synthesis routes. This work presents a conversion methodology to produce bioethanol from carrot and broccoli residues and from their mixture; the samples of vegetable wastes has been collected in the municipality of Guanajuato, Mexico. Using the 1H NMR technique, the characteristic signals of bioethanol are identified. On the other hand, using the UV-VIS spectrophotometry technique, a maximum of 25.63 mg of total sugar content has been determined for the mixture. Likewise, a maximum bioethanol concentration of 60.6 g/L is obtained. From a refractometry and HPLC study, a conversion to bioethanol of 34.8% is determined for the mixture of residues. This work analyses the potential of broccoli and carrot residues for bioethanol production, either as isolated or as mixed wastes. This work presents a conversion methodology to produce bioethanol from carrot and broccoli residues and from the mixture of both residues. The vegetable waste has been collected in the municipality of Guanajuato, Mexico. Conversions to ethanol of 21.10%, 26.72%, and 34.82% were obtained for carrot and broccoli residues, and their mixture, respectively.image