Fabrication of CuFe2O4/Bi12O17Cl2 photocatalyst with intrinsic p-n junction for highly efficient bisphenol A degradation.

The construction and application of novel highly efficient photocatalysts have been the focus in the field of environmental pollutant removal. In this work, a novel CuFe2O4/Bi12O17Cl2 photocatalysts were synthesized by simple hydrothermal and chemical precipitation method. The fabricated CuFe2O4/Bi12O17Cl2 composite exhibited much higher photocatalytic activity than pristine CuFe2O4 and Bi12O17Cl2 in the removal of bisphenol A (BPA) under visible-light illumination, which ascribed to the intrinsic p-n junction of CuFe2O4 and Bi12O17Cl2. The photocatalytic degradation rate of BPA on CuFe2O4/Bi12O17Cl2 with an optimized CuFe2O4 content (1.0 wt.%) reached 93.0% within 30 min. The capture experiments of active species confirmed that the hydroxyl radicals (•OH) and superoxide radicals (•O2-) played crucial roles in photocatalytic BPA degradation process. Furthermore, the possible degradation mechanism and pathways of BPA was proposed according to the detected intermediates in photocatalytic reaction process.