Photo-sensitive CuS/NiO heterostructure electrocatalysts for energy-saving hydrogen evolution reaction at all pH conditions

Heterostructures based on transition metal chalcogenides/oxides have gained significant interest in the application of electrochemical hydrogen evolution reaction (HER) due to their distinct characteristics and excellent electrocatalytic activity. Herein, we developed an earth-abundant, low-cost, and light-sensitive CuS/NiO (CSNO) heterostructure electrocatalyst via a facile co-precipitation method and fabricated it on silver-modified conducting cellulose paper for HER. Under all pH level, the performance of the visible light-sensitive HER catalyst has been examined. With the illumination of light, HER performance at all pH, which conserves energy has been seen. In basic media, the value of overpotential was improved to −290 mV vs RHE at 20 mA/cm2 under light-illuminating conditions. Similarly, with light illumination, the overpotential of the CSNO10/Ag- modified paper is reduced to −363 mV and −312 mV vs RHE in an acidic and in a near-neutral medium, respectively. In addition to that, the values of the Tafel slopes and charge-transfer resistance also decreased indicating relatively faster HER kinetics in the presence of light at all pH levels. Also, The CSNO10 electrode exhibits stability of more than 24 h in 1 M PBS with an overpotential of −368 mV vs RHE at 20 mA/cm2. The overall performance of the CuS/NiO heterostructure is a good sign to be explored it as a low-cost and efficient electrocatalyst for the large-scale production of green hydrogen (H2).