Direct numerical analysis of dynamic facilitation in glass-forming liquids

arXiv (Cornell University)(2023)

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摘要
We propose a computational strategy to quantify the temperature evolution of the timescales and lengthscales over which dynamic facilitation affects the relaxation dynamics of glass-forming liquids at low temperatures, that requires no assumption about the nature of the dynamics. In two glass models, we find that dynamic facilitation depends strongly on temperature, leading to a subdiffusive spreading of relaxation events which we characterize using a temperature-dependent dynamic exponent. We also establish that this temperature evolution represents a major contribution to the increase of the structural relaxation time.
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关键词
liquids,numerical analysis,direct numerical analysis,glass-forming
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