Magneto-structural studies on [CuII2{L3-(μ2-1,1-CO2–)2}2]•MeOH•H2O and [CuII4{L4-(μ2-1,3-CO2–)(μ2-1,3-CO2Me)}4](ClO4)4 using carboxylate- / carboxymethylester-appended (2-pyridyl)-alkylamine ligands differing in alkyl chain length

Shashi Kant,Munirathnam Manda,Narottam Mukhopadhyay,Himanshu Arora,Indresh Verma,Francesc Lloret,Rabindranath Mukherjee

Polyhedron（2023）

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摘要

Structural and magnetic studies have been done on a dicopper(II) and a tetracopper(II) molecular square; the two Cu(II) centres and four Cu(II) centres, respectively, are anti- and ferromagnetically coupled.

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关键词

Dimer, Tetramer, Carboxylate as bridging ligand, Crystal structures, Anti, and ferromagnetic exchange coupling

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