Synthesis and in vitro anticancer studies of arene ruthenium(II) and arene osmium(II) complexes bearing arsine and stibine co-ligands on breast cancer cell-lines

Stefan Latiş,Christoph Marschner,Judith Baumgartner,Sharon Prince,Supratim Biswas,Suparna Chakraborty,Kimberly G. Garcia,Ron M.A. Heeren,Sebastiaan Van Nuffel,Burgert Blom

Journal of Organometallic Chemistry（2023）

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摘要

•Rare examples of arene Os(II) stibine and arsine complexes reported.•First in vitro cytotoxic studies of arene Ru(II) and Os(II) stibine and arsine complexes.•Several complexes out perform cisplatin and exhibit good selectivity.•Incorporation of SnCl3 into the coordination sphere of Ru(II) and Os(II).•ToF-SIMS investigations offer insights into speciation.

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关键词

rutheniumii,complexes,anticancer studies,arsine,co-ligands,cell-lines

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