Synthesis of η2-platinum complexes on the rim of open-cage fullerenes

Journal of Organometallic Chemistry（2023）

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摘要

•Open-cage fullerene derivatives react readily with ortho-phenylenediamine.•Open-cage fullerenes form stable mono-Pt and bis-Pt complexes.•Fullerene CC on the rim of the orifice form η2-type coordination complex with Pt.

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关键词

Fullerene,Open-cage,Platinum complex,Ortho-phenyldiamine,Host-guest,Quinoxaline

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