Loofah-inspired sodium alginate/carboxymethyl cellulose sodium-based porous frame for all-weather super-viscous crude oil adsorption and wastewater treatment in harsh environment

Solar-driven viscosity reduction of highly viscous crude oil has emerged as an environmentally friendly method to address large-scale oil spills. However, the challenge lies in the limited availability of sunlight during cloudy days and at night, which hinders the effectiveness of green advanced porous materials. This study developed all-weather-available advanced porous materials in the form of loofah-like structured porous frame composed of 1H, 1H, 2H, 2H-perfluorooctyltriethoxysilane/MXene/carbon nanotubes (CNTs)/sodium alginate (SA)/carbox-ymethyl cellulose sodium (NaCMC). MXene and CNTs formed a continuous and stable network that enabled PMCSCPs to rapidly reduce crude oil viscosity for all-day based on photothermal and electrothermal conversions. Additionally, loofah-like porous structure and oriented pipeline biomass skeleton endowed PMCSCPs with stable and rapid adsorption capacity and speed. Considering the complexity of the external environment and oily wastewater composition, we verified the separation performance of PMCSCPs for metal ions and dyes and the ice-breaking ability under icy conditions. PMCSCPs provided a novel approach to achieving clean, high -efficiency, all-day remediation of ultra-viscous crude oil. This "Three birds with one stone" approach is ex-pected to be obtained from nature and used on a large scale, replacing conventional porous adsorbent materials.