Semicarbazones of alkyl 3-nitropyruvates: Synthesis and structural features

Mendeleev Communications(2023)

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摘要
Semicarbazones of alkyl 3-nitropyruvates were obtained by the reaction between alkyl 3-bromo-3-nitroacrylates and semicarbazides. The products were formed as E/Z isomer mixtures from which some representatives of the individual isomers were isolated. The possibility of their isomerization was shown.
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关键词
nitroacrylates, semicarbazides, nucleophilic addition, aza-Michael adduct, elimination, semicarbazones, nitropyruvates
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