High-mass-loading cobalt iron phosphide@nickel vanadium layered double hydroxide heterogeneous nanosheet arrays for hybrid supercapacitors
JOURNAL OF COLLOID AND INTERFACE SCIENCE(2024)
摘要
Designing multidimensional heterostructures on flexible substrates is an efficient approach to resolve the low energy density of supercapacitors. Herein, a three-dimensional (3D) porous cobalt iron phosphide (CoFeP) @nickel vanadium-layered double hydroxide (NiV-LDH) heterostructure has been prepared anchored on carbon cloth (CC) substrate. In this nanoarchitecture, NiV-LDH nanosheets are densely wrapped on the surface of CoFeP nanosheets, which forms a hierarchically porous framework with an enlarged surface area and accessible pore channels. Benefiting from the strong interaction and synergistic effect between CoFeP and NiV-LDH, the welldefined heterostructure can realize simultaneously rich redox active sites, rapid reaction dynamics, and good structural stability. Thus, the binder-free CoFeP@NiV-LDH electrode with a high mass loading of 6.47 mg cm-2 displays a significantly increased specific capacity of 903.1C g- 1 (2.35C cm-2) at 1 A g-1 and enhanced rate capability when compared to pristine CoFeP and NiV-LDH. Additionally, the assembled hybrid supercapacitor (HSC) yields an energy density of 77.9 Wh kg-1/0.98 Wh cm-2 and excellent long-term stability. This research proposes a rational route for designing heterogeneous micro-/nanoarchitectures with commercial-level mass loading for the practical application of high-energy-density supercapacitors.
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关键词
Transition metal phosphides,Layered double hydroxide,Heterostructure,Electrochemical performance,Supercapacitors
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