The peculiar SHG behaviour of Co-5,10,15,20-tetraphenilporphyrinate in the solid state. An experimental and theoretical study
JOURNAL OF MOLECULAR STRUCTURE(2023)
摘要
•Increase of SHG signal of Co-tetraphenylporphirinate under a 1.907 μm pulsed laser radiation.•Theoretical calculations on CoTPP fragments simulate appropriately the SHG responses.•The enhancement of the SHG signal is imputable to an electronic or spin transition.
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关键词
Metal porphyrinates,SHG properties,Theoretical calculations,NLO properties,Structure-properties relashionship
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