Controllable Si–C Bond Formation from Trihydrosilanes En Route to Synthesis of 1,4-Azasilinanes with Diverse Silyl Functionalities

Jiawei Guo,Shunfa Liu,Jun Jing,Yu Fan, Yingdong Fu, Shiyang Liu,Wanshu Wang,Lu Gao,Zhenlei Song

Organic letters（2023）

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摘要

A B(CF)-catalyzed controllable inter/intra-/intermolecular Si-C bond formation process has been developed from trihydrosilane and dienamide with alkenes, anilines, or aryl iodides. A variety of 1,4-azasilinanes have been generated with diverse -cyclic heteroleptic disubstitutions on silicon, thereby expanding the range of silaazacyclic rings available for the discovery of silicon-containing drugs.

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关键词

diverse silyl functionalities,trihydrosilanes en route,controllable si–c,synthesis

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