Challenging metal-ion rocking-chair and zinc-ion mechanisms in mild acidic to neutral aqueous electrolytes

Arvinder Singh, David Grenz,Yann Pellegrin,Fabrice Odobel,Philippe Poizot,Joël Gaubicher

Electrochemistry Communications（2023）

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摘要

•2,5-Ditertbutyl hydroquinone studied for the 1st time in aqueous zinc batteries.•DTBHQ exhibits a record low solubility of 629 µM/L, ensuring remarkable capacity retention.•Overwhelming proton insertion mechanism challenges the zinc-ion mechanism.•Reduction potential proportional to pKa values of the proton source.

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关键词

mild acidic,metal-ion,rocking-chair,zinc-ion

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