Distinctive Arbutin‐Containing Markers: Chemotaxonomic Significance and Insights Into the Evolution of Proteaceae Phytochemistry

Natural products isolation studies of eight endemic Tasmanian Proteaceae species – Agastachys odorata, Persoonia juniperina, Hakea megadenia, Hakea epiglottis, Orites diversifolius, Orites acicularis,Orites revolutus, and Telopea truncata – and three endemic Australian Proteaceae species Banksia serrata, Banksia praemorsa, and Banksia marginata were undertaken.Two previously unreported glycoside‐derived natural products were identified, in addition to four other tremendously rare arbutin esters. The results of this study provide further evidence consistent with the proposal that these distinctive arbutin esters represent markers that can provide valuable insights into the chemical evolution of plant species within the family Proteaceae.