Deep eutectic solvent-infused two-dimensional metal-organic framework membranes as quasi-solid-state electrolytes for wearable micro-supercapacitors.

The burgeoning field of miniaturized and portable electronic devices calls for novel advances in micro-energy storage technology. Micro-supercapacitors (MSC) stand at the forefront of this endeavour, yet unlocking their full potential necessitates the exploration of high-performance electrolytes. Herein, we introduce a strategy that leverages flexible metal-organic framework (MOF, CuTCPP) nanosheet-based membranes to construct quasi-solid-state electrolytes (QSSEs) and enhance the ionic conductivity and electrochemical performance of deep eutectic solvent (DES)-based MSCs. Owing to the multiple nanochannel pathways provided by the porous MOF nanosheets, the ionic conductivity of DES within the nanochannels exhibits a 13-fold increment compared with its bulk counterpart. Furthermore, we engineered MSC harnessing the CuTCPP-DES system, whose performance surpasses that reported for most of the ionic liquid and 2D material-based MSCs. The areal-specific capacitance was 81.3 mF cm at a current density of 0.1 mA cm, and the energy density was 45.17 μW h cm at a power density of 8.559 mW cm. Notably, the performance of MSCs remains consistent and unaffected, even when subjected to bending. These findings contribute to the exploration and potential optimization of the inherent benefits of MOFs, thereby presenting a paradigm shift in nanoconfined systems for microscale energy storage applications.