Novel Aspects about "Lifetime" in Upconversion Luminescence

Recent progress on the temporal response (TR) of lanthanide-doped upconversion luminescence (UCL) has enriched the means of UCL regulation, promoted advanced designs for customized applications such as biological diagnosis, high-capacity optical coding, and dynamic optical anti-counterfeiting, and pushed us to reacquaint the dynamic responses of sensitizer/activator ions in UCL systems. In particular, the lifetime of UCL should be revisited after discovery of novel experimental phenomena and luminescence mechanisms, i. e., it should be understood as the collective TR (in the decay edge) of all the involved ions rather than the reciprocal of the radiative rate of an individual ion. In this Concept, we retraced the latest understanding of the dynamics in UCL with special attention to the relationship between excitation and emission, means of TR regulation, and discussed existing challenges. It is expected to provide some fundamental insights to deepened understanding, further regulation, and frontier applications of TR features of UCL. This Concept briefly reviews recent advances in temporal response (TR) and lifetime of upconversion luminescence, including lifetime control methods, relation of excitation and de-excitation, the impact of TR on luminescence spectra, and proposes future challengesthat need to be addressed, in order to raise more attention to the development of this field and relevant applications using TR characteristics.image