On the thermal response of multiscale nanodomains formed in trans-anethol/ethanol/water surfactant-free microemulsion

With increasing temperature, the ternary system shows extended areas in the monophasic zone. We demonstrate that the phase behavior and the multiscale nanodomains formed in the monophasic zone can be precisely and reversibly tuned by altering the temperature. Increasing temperature can destroy the stability of the multiscale nanodomains in equilibrium, with an exponential decay in the scattering light intensity. Nevertheless, molecular-scale aggregates and mesoscopic droplets exhibit significantly different response behaviors to temperature stimuli. The temperature-sensitive nature of the ternary SFME system provides a crucial step forward exploring and industrializing its stability.