Oxidation of 3‐Oxo‐N‐Confused Porphyrin with PIFA: Inner and meso Functionalizations

Yihuan Zhang,Haoran Liu,Huowang He,Bo Zou, Zhaofen Zhai,Taoxing Yu,Atsuhiro Osuka,Hua‐Wei Jiang

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY（2023）

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摘要

Conjugate addition of ethanol and subsequent oxidation with [bis (trifluoroacetoxy)iodo]benzene (PIFA) allowed for the inner ethoxylation of 3-oxo-N-confused tetraphenylporphyrin (ONCP). First oxidation of ONCP with PIFA followed by treatment with ethanol gave two more N-confused phlorins derivatives 5 and 6.

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关键词

Michael addition,oxidation,phlorin,PIFA,porphyrinoids

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