Crystallization of Zr-Based Amorphous Alloys in Laser Welding

Crystallization often occurs in the laser welding of amorphous alloys, reducing the properties of amorphous alloys. Therefore, the research in this thesis focuses on the experimental selection of suitable welding parameters to prevent crystallization of Zr-based amorphous alloys during the laser welding process. As such, it is necessary to simulate the temperature field curve of the welding area by computer and then determine the power and laser moving speed of laser welding. In this paper, the temperature field curve of the Zr41.2Ti13.8Cu12.5Ni10Be22.5 (Vit1) amorphous alloy in laser welding is obtained by finite element analysis. The continuous heating curve (CHT) of Vit1 is fitted by the Vogel-Fulcher-Tammann (VFT) equation and the Kissinger equation. If the temperature field curve intersects with the CHT curve, crystallization occurs. The experiment results show that the VFT equation can be used to predict the crystallization of Vit1 better in laser welding. The temperature and welding time are increased by using a low welding speed. Therefore, the temperature of the weld zone cannot fall in time, resulting in the intersection of the temperature field curve and the CHT curve. Thus, crystallization can be avoided if the welding speed is controlled within a reasonable range, and the highest temperature is kept under the CHT curve. The combination of the CHT curve and the temperature field curve shows that the samples at 300 W-3 mm/s and 300 W-6 mm/s welding parameters all undergo crystallization, while the samples at 300 W-9 mm/s and 300 W-12 mm/s welding parameters do not undergo crystallization. Through the flexural test, it is found that the flexural strength of the welded interface is at its the maximum under 300 W-9 mm/s.