Metal-mediated tunability of MOF-based optical modulators

Nikita K. K. Kulachenkov, Bogdan Orlioglo,Eugene S. S. Vasilyev, Svyatoslav A. A. Povarov,Alexander M. M. Agafontsev,Semyon Bachinin,Sergei Shipilovskikh,Artem Lunev,Denis G. G. Samsonenko,Vladimir P. P. Fedin,Konstantin A. A. Kovalenko,Valentin A. A. Milichko

CHEMICAL COMMUNICATIONS（2023）

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摘要

We report on the design of 1D MOFs based on a nopinane-annelated organic ligand and Co(ii) or Ni(ii), the variation of which allows tuning the optical modulation bandwidth. Structural and time-resolved analysis revealed the optical modulation mechanism, the rates and its endurance, thereby enriching the list of sustainable MOFs for tunable optical modulators.

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关键词

tunability,metal-mediated,mof-based

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