Organic matter sources to the superficial sediment of the itapicuru river estuary (bahia- brazil).

Juliana de Souza Santana, Iasmim de Deus Gargur Leal,Antonio Fernando de Souza Queiroz, Henrique Cesar Pereira Assumpcao, Jose Roberto Bispo de Souza,Maria do Rosario Zucchi,Ana Cecilia Rizzatti de Albergaria-Barbosa

QUIMICA NOVA(2023)

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摘要
ORGANIC MATTER SOURCES TO THE SUPERFICIAL SEDIMENT OF THE ITAPICURU RIVER ESTUARY (BAHIA -BRAZIL). The present study evaluated the sources of organic matter (O.M.) in the Itapicuru River estuary (IRE), which is in an environmentally protected area surrounded by the Atlantic Rainforest in the northeast of Brazil. Eleven sediment samples were collected along the study area. Total organic carbon (TOC) and the 813C values were determined using an elemental analyzer coupled with an isotope ratio mass spectrometer. The n-alkanes composition was evaluated through gas chromatography coupled to a flame ionization detector. TOC and total n-alkanes concentrations ranged, respectively, from not detected to 0.72%, and from lower the limit of detection to 5024 ng g-1. There was a significant concentration of n-C22 and n-C24 in some samples showing bacterial production and recycling of O.M. Values of 813C ranged from -27.6 to -21.9%& DEG;. Carbon preference index, terrestrial-aquatic ratio, aquatic production index, average chain length, and the ratio between n-C29 and n-C31 values ranged, respectively, from 1.42 to 4.11; 2.82 to 9.40; 0.00 to 0.25; 27.7 to 29.9; and 0.27 to 0.43. These results show that concentrations of O.M. to IRE are low, and its main source is C3 plants, such as those from mangroves. There is also the contribution of macrophytes.
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关键词
estuary, n -alkanes, organic matter, rainforest
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