Pore structure evolution of tar-rich coal with temperature-pressure controlled simulation experiments

FUEL(2023)

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摘要
Tar-rich coal, with a tar yield of 7-12%, has significant potential for hydrocarbon resources. In this study, typical tar-rich coal samples from Daliuta mining area were selected as the research object to conduct temper-ature-pressure controlled simulation experiments that simulated stratigraphic conditions. The pore character-istics of the tar-rich coal during coal metamorphism were studied, and the pore evolution law of the tar-rich coal was revealed. The findings demonstrate that this experiment successfully simulates all coal ranks, from low coal rank to high coal rank. Tar-rich coals contain pores of five different genetic types. Gas pores and fissures exhibit a tendency toward growth, while cellular pores are gradually broken and collapsed by compaction, showing a tendency to reduce pores. Mold pores and intergranular pores remain basically unchanged. According to the quantitative analysis of pore structure, each pore has a different evolutionary pattern. Macropores are the pri-mary source of pore volume, micropores are the most active pore component in evolution, and mesopores exhibit a diminishing and then growing "U" shape characteristic. Three phases of tar-rich coal pore evolution-Ro, max < 0.9%, R-o,R- max = 0.9-3%, and R-o,R- max> 3%-can be distinguished, and there is a strong correlation between these stages and the coalification jumps.
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关键词
pore structure evolution,coal,tar-rich,temperature-pressure
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