Aqua-{μ-1,4-bis-[(1,4,7,10-tetra-aza-cyclo-dodecan-1-yl)meth-yl]benzene}(nitrato-κ O )dicopper(II) tris-(nitrate) trihydrate.

Yoshimi Ichimaru,Koichi Kato,Kirara Sugiura, Sarina Ogawa,Wanchun Jin,Masaaki Kurihara,Yoshihiro Yamaguchi,Masanori Imai,Hiromasa Kurosaki

IUCrData（2023）

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摘要

In the title dinuclear Cu complex, [Cu(NO)(CHN)(HO)](NO)·3HO, the two Cu mol-ecules both have a square-pyramidal geometry, but the ligands in the axial positions are different: a water mol-ecule and a nitrate ion. All nitrate ions, water mol-ecules, and N-H groups are involved in an inter-molecular hydrogen-bond network.

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关键词

crystal structure,copper(ii) complex,cyclen,p-xylene,dinuclear complex

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