A hybrid double perovskite ferroelastic exhibiting the highest number of orientation states.

Wei-Jian Xu,Pavel Zelenovskii,Alexander Tselev,Luis Verissimo,Konstantin Romanyuk,Wei Yuan,Wei-Xiong Zhang,Andrei Kholkin,João Rocha

Chemical communications (Cambridge, England)（2023）

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摘要

Integrating NH as a B'-site ion within a three-dimensional double hybrid perovskite resulted in a novel high-temperature ferroelastic, (MeNOH)(NH)[Co(CN)], which uniquely demonstrates a reversible triclinic-to-cubic phase transition at 369 K and offers a record-setting 24 orientation states, the highest ever reported among all ferroelastics.

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hybrid double perovskite

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