Biofilms retard the desorption of benzo(a)pyrene from polyethylene pellets in the marine environment

Marine pollution bulletin(2023)

引用 0|浏览15
暂无评分
摘要
Microplastics are emerging as vectors for the transport hydrophobic organic compounds (HOCs) in aquatic environments, however, their impact is poorly understood due to the lack of field studies. In this study, the pristine and benzo(a)pyrene (B[a]P) adsorbed polyethylene (PE) pellets were placed at Haihe Estuary (Tianjin, China) for 80 days to investigate desorption behavior. Combining laboratory and in situ experiments, this study firstly verified that the intra-particle diffusion was the rate-limiting step for the desorption process of B[a]P from PE microplastics under different environmental conditions. By hindering the desorption and modifying MPs surface, biofilm might play a key role in desorption process, leading to the apparent hysteresis of the field desorption process at our time scale. Potential degradation of the polymer and B[a]P by biofilms, however, would support continuing desorption. The study explored the interaction of biofilm and MPs-contaminants mixture and its implications for the environmental fate of HOCs.
更多
查看译文
关键词
Microplastics,Biofilm,Desorption,Polycyclic aromatic hydrocarbon,Pollutant carrier
AI 理解论文
溯源树
样例
生成溯源树,研究论文发展脉络