Modulation of the structure of octahedral 1,3-pdta-nickel(II) complex by introducing methyl substituents at the central 1,3-propanediamine carbon atom: Stereospecific formation and the crystal structure of [Mg(H2O)5Ni(2,2-diMe-1,3-pdta)]·1.5H2O

Sonja Ž. Đurić,Beata Warżajtis,Nenad S. Drašković,Nada D. Savić,Dejan M. Gurešić,Urszula Rychlewska,Miloš I. Djuran

Polyhedron（2020）

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摘要

Spectroscopic and crystallographic characterization of [Mg(H2O)5Ni(2,2-diMe-1,3-pdta)].1.5H2O complex and comparison of its structural characteristics with those for the analogues 1,3-pdta- and 1,3-pndta-Ni(II) complexes.

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关键词

1,3-pdta,2,2-diMe-1,3-pdta,Nickel(II) complexes,Spectroscopic characterization,X-ray crystallography

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