The direct synthesis of dimethyl carbonate out of carbon dioxide and methanol is catalyzed by D-metals supported on various matrices

Douglas José Faria,Leonardo Moreira dos Santos,Franciele Longaray Bernard,Ingrid Selbacch Pinto,Vitaly V. Chaban,Ivan Pacheco Romero,Sandra Einloft

Journal of Molecular Structure（2023）

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摘要

•The ES-Fe sample demonstrated a methanol conversion rate of 12.7% with 100% selectivity.•The ES-Cu sample exhibited a yield of 11.3% with 100% selectivity.•The catalytic action of the ES-Fe catalyst remained stable upon recycling.•Biomass residues prove to be an excellent matrix for the impregnation of metals such as fe and cu.

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关键词

Dimethyl carbonate,CO2,Methanol,Catalysts,Synthesis

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