Photocatalytic Intramolecular Alkene Hydroamination of N -Alkoxy Ureas: An Approach to Imidazolinones.
The Journal of organic chemistry(2023)
摘要
Imidazolinones were obtained in good yields by intramolecular hydroamination of -alkoxy ureas in the presence of an organic photocatalyst and an inorganic base. In this reaction, the -alkoxy urea anion generated by deprotonation undergoes photocatalyzed single-electron-transfer oxidation to generate the corresponding radical, which cyclizes to afford the imidazolinone ring. This new protocol grants access to an array of complex molecules containing a privileged imidazolinone core.
更多查看译文
AI 理解论文
溯源树
样例
![](https://originalfileserver.aminer.cn/sys/aminer/pubs/mrt_preview.jpeg)
生成溯源树,研究论文发展脉络
Chat Paper
正在生成论文摘要