Atroposelectivity with two catalysts

NATURE SYNTHESIS（2023）

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摘要

Synthesis of chiral aryl–alkene bond axes is a challenge owing to axial instability and specific substrate requirements. Now, arylboration of alkynes by sequentially using two catalysts yields axially chiral alkenylboronates with excellent stereocontrol.

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关键词

Asymmetric catalysis,Synthetic chemistry methodology,Chemistry/Food Science,general

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