Application of TNBA-based low eutectic mixture in melt-cast explosives

In this work, two TNBA-based low eutectic mixtures, TNBA/TNAZ (TZ) and TNBA/DNTF (TD), as well as eight TNBA-based melt-cast explosives, TNBA/TNAZ/RDX (TZR), TNBA/TNAZ/HMX (TZH), TNBA/TNAZ/TKX-50 (TZT), TNBA/TNAZ/CL-20 (TZC), TNBA/DNTF/RDX (TDR), TNBA/DNTF/HMX (TDH), TNBA/DNTF/TKX-50 (TDT) and TNBA/DNTF/CL-20 (TDC), were developed as structural models. A molecular dynamics approach was used to model the cohesive energy density, binding energy, and mechanical properties of these explosives. Moreover the thermal decomposition properties and mechanical sensitivity were characterized via DSC and mechanical sensitivity tests. Finally, the EXPLO-5 software predicted the detonation properties and detonation products of the aforementioned 10 mixed explosive systems. The results showed that the four mixed explosives of TDT, TDH, TZC, and TDR had excellent performance in cohesive energy density, binding energy, and material rigidity, respectively. The temperature difference was comparatively significant between the melting temperature and decomposition temperature of the eight types of mixed explosives, up to 170.60 K, with TDH and TZH having the highest thermal decomposition temperature at approximately 520 K. The six kinds of mixed explosives of TZR, TZH, TZT, TDR, TDH, and TDT had moderate mechanical sensitivities. . The five types of mixed explosives, TZT, TZC, TDH, TDT, and TDC, had the greatest detonation velocity.