Reversible structural transformations and color-tunable emissions in organic manganese halides.

Yu-Hang Liu,Yi-Fan Wu,Li-Juan Feng, Rui-Rui Zhao, Shan-Xiao Wang,Ming-Ming Zhang, Dan-Yang Wang, Xiang-Wen Kong,Xiao-Wu Lei

Chemical communications (Cambridge, England)（2023）

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摘要

Herein, we for the first time report a reversible conversion between green-emissive [DMPZ]MnCl and red-emissive [DMPZ](MnCl)(MnCl)(HO) (DMPZ = 1,4-dimethylpiperazine) using kinetic and thermodynamic controlling strategies. Significantly, the synchronous structural and emission transformations in single-component organic manganese halides with adjustable emission colors are highlighted.

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关键词

organic manganese,reversible structural transformations,emissions,color-tunable

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