catena-Poly[[chloridotris(1,3-thiazolidine-2-thione-κS)cadmium(II)]-μ-chlorido]

Aboubacar Diop,Tidiane Diop,Antoine Blaise Kama, Cheikh Abdou Khadre Diop, Nikolay Tumanov

IUCrData（2020）

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摘要

The synthesis and characterization of poly[dichloridotri(1,3-thiazolidine-2-thione)cadmium(II)], [CdCl2(C3H5NS2)3]n, prepared from CdCl2·H2O and C3H5NS2 (tzdSH) in a 1:3 ratio, are described. The CdII cation is coordinated by three 1,3-thiazolidine-2-thione molecules and three Cl− anions in a distorted octahedral environment. The Cd metal centres are connected via Cl− ligands, creating polymeric chains running along the a-axis direction. The conformation of the chains is stabilized by N—H⋯Cl hydrogen bonds.Unlabelled Image

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关键词

crystal structure,1,3-thiazolidine-2-thione,cadmium centre,hydrogen bonding

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catena-Poly[[chlorido­tris­(1,3-thia­zolidine-2-thione-κS)cadmium(II)]-μ-chlorido]

catena-Poly[[chloridotris(1,3-thiazolidine-2-thione-κS)cadmium(II)]-μ-chlorido]