Stabilization of high-temperature superconducting A15 phase La$_4$H$_{23}$ below 100 GPa

High pressure plays a crucial role in the field of superconductivity. Compressed hydride superconductors are leaders in the race for a material that can conduct electricity without resistance at high or even room temperature. Different synthetic paths under pressure will drive the formation of different polyhydrides. In the present work, through precise control of the synthesis pathway, we have discovered new lanthanum superhydride, cubic A15-type La$_4$H$_{23}$, with lower stabilization pressure compared to the reported $\textit{fcc}$ LaH$_{10}$. Superconducting La$_4$H$_{23}$ was obtained by laser heating of LaH$_3$ with ammonia borane at about 120 GPa. Transport measurements reveal the maximum critical temperature $\textit{T}$$_{C}$(onset) = 105 K at 118 GPa, as evidenced by the sharp drop of electrical resistance and the displacement of superconducting transitions in applied magnetic fields. Extrapolated upper critical field $\textit{B}$$_{C2}$(0) of La$_4$H$_{23}$ is about 33 T at 114 GPa in agreement with theoretical estimates. Discovered lanthanum hydride is a new member of the A15 family of superconductors with $\textit{T}$$_C$ exceeding the boiling point of liquid nitrogen.