Discovery and structural assignment of (S)-sydosine from amphipod-derived Aspergillus sydowii MBC15-11F through HRMS, advanced Mosher and molecular modelling analyses.

Mallique Qader,Larry L Mweetwa,Teppo Rämä,Bathini Thissera,Bruce F Milne,Usama R Abdelmohsen,Raha Orfali,Ahmed Tawfike,Manal Esheli,Emmanuel T Oluwabusola,Lalith Jaysainghe,Marcel Jaspars,Mostafa E Rateb

Journal of applied microbiology（2023）

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摘要

Fermentation of A. sydowii yielded a new (S)-sydosine and known metabolites as predicted by HRESIMS-aided dereplication. Molecular modelling prediction of the absolute configuration of 1 agreed with advanced Mosher analysis.

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关键词

Aspergillus sydowii, deap-sea, (S)-sydosine, HRMS, dereplication, molecular modelling

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