Tailoring Interfacial Lewis Acid-Basic Pair on ZnO/4Mg1ZrOx Allows Dehydrogenative α-Methylenation of Alcohols with Methanol to Allylic Alcohols

Qiang Liu,Aixiao Fu,Mengqing Sun,Shifeng Jiang,Lingling Zhao,Xiuyun Liu,Xiaoran Liu,Xicheng Wang,Xindong Mu,Guoqiang Xu

Applied Catalysis A: General（2020）

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摘要

•ZnO/4Mg1ZrOx mixed oxide was synthesized and applied in the dehydrogenative α-methylenation of alcohols with methanol to produce allylic alcohols.•Surface Lewis acid-basic pair was characterized and its key roles in allowing high catalytic selectivity to allylic alcohols were demonstrated.•Alcohol dehydrogenative α-methylenation with methanol was facilitated by the MPV-type selective hydrogen transfer process.

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关键词

alcohols,allylic alcohols,dehydrogenative coupling,hydrogen transfer,mixed oxide

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