Visible-light-mediated -amino alkylation of ketimines and aldimines for the synthesis of 1,2-diamines

A visible-light-mediated protocol to prepare 1,2-diamines has been successfully explored based on the photoredox/Bronsted acid co-catalyzed & alpha;-amino alkylations of imines with tertiary amines. Both ketimines and aldimines are applicable to this transformation. Various 1,2-diamines with different functional groups were produced in moderate to excellent yields. Moreover, this approach could be performed on a gram scale, showing its practicality.