Effect of the anion in phosphonium-based ionic liquids to recovery efficiently 2-propanol from an azeotropic mixture with water

M.A. Pilar Cumplido,Javier De la Torre,Josep P. Cerisuelo,Amparo Chafer

Fluid Phase Equilibria（2023）

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摘要

•LLE data of water+2-propanol+[TDTHP][Phosph], [TDTHP][Cl] or [TDTHP][Br].•Study of temperature influence on systems.•The NRTL and UNIQUAC models were applied to correlate the studied system.•Influence of anion and their size on the LLE was discussed.•Study of the capability of the ionic liquids to separate the alcohol + water mixture.

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关键词

ionic liquids,azeotropic mixture,phosphonium-based

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