Bis(1-methyl-ortho-carboranyl)borane.

Manjur Akram,John Tidwell,Jason Dutton,Caleb D Martin

Angewandte Chemie (International ed. in English)（2023）

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摘要

The Lewis superacid, bis(1-methyl-ortho-carboranyl)borane, is rapidly accessed in two steps. It is a very effective hydroboration reagent capable of B-H addition to alkenes, alkynes, and cyclopropanes. To date, this is the first Lewis superacidic secondary borane and most reactive neutral hydroboration reagent.

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关键词

bis1‐methyl‐ortho‐carboranylborane

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