Recent Advances in Laser-Induced Synthesis of MOF Derivatives

Metal-organic frameworks (MOFs) are crystalline materials with permanent pores constructed by the self-assembly of organic ligands and metal clusters through coordination bonds. Due to their diversity and tunability, MOFs are used as precursors to be converted into other types of functional materials by pyrolytic recrystallization. Laser-induced synthesis is proven to be a powerful pyrolytic processing technique with fast and accurate laser irradiation, low loss, high efficiency, selectivity, and programmability, which endow MOF derivatives with new features. Laser-induced MOF derivatives exhibit high versatility in multidisciplinary research fields. In this review, first, the basic principles of laser smelting and the types of materials for laser preparation of MOF derivatives are briefly introduced. Subsequently, it is focused on the peculiarity of the engineering of structural defects and their applications in catalysis, environmental protection, and energy fields. Finally, the challenges and opportunities at the current stage are highlighted with the aim of elucidating the future direction of the rapidly growing field of laser-induced synthesis of MOF derivatives. Metal-organic framework (MOF) derivatives show excellent diversity and tunability and thus are promising materials for catalytic, environmental, and energy-related applications. Laser-induced synthesis endows MOF derivatives with new features due to their high efficiency, selectivity, and programmability. In this paper, state-of-the-art advances in laser-induced synthesis of MOF derivatives are reviewed, and the structure-effect relationships and functional applications are highlighted.image