Complexation with pagoda[ n ]arene ( n = 4, 5) protects ferrocenium from oxidation.

Gui-Hua Chen,Yi-Meng Duan,Ying Li,Xiao-Ni Han,Kun-Peng Wang,Zhi-Qiang Hu,Chuan-Feng Chen

Chemical communications (Cambridge, England)（2023）

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摘要

The complexation behaviors of pagoda[]arenes ( = 4, 5) with ferrocene, ferrocenium and analogues cobaltocenium were studied. The inclusion complexes of pagoda[]arenes can protect ferrocenium from oxidation in organic solvents and improve the stability and oxygen resistance of ferrocenium.

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